您可以使用jnativehook:https://github.com/kwhat/jnativehook

示例:

import org.jnativehook.GlobalScreen;
import org.jnativehook.NativeHookException;
import org.jnativehook.keyboard.NativeKeyEvent;
import org.jnativehook.keyboard.NativeKeyListener;

public class GlobalKeyListenerExample implements NativeKeyListener {
    public void nativeKeyPressed(NativeKeyEvent e) {
        System.out.println("Key Pressed: " + NativeKeyEvent.getKeyText(e.getKeyCode()));

        if (e.getKeyCode() == NativeKeyEvent.VK_ESCAPE) {
            GlobalScreen.unregisterNativeHook();
        }
    }

    public void nativeKeyReleased(NativeKeyEvent e) {
        System.out.println("Key Released: " + NativeKeyEvent.getKeyText(e.getKeyCode()));
    }

    public void nativeKeyTyped(NativeKeyEvent e) {
        System.out.println("Key Typed: " + e.getKeyText(e.getKeyCode()));
    }

    public static void main(String[] args) {
        try {
            GlobalScreen.registerNativeHook();
        }
        catch (NativeHookException ex) {
            System.err.println("There was a problem registering the native hook.");
            System.err.println(ex.getMessage());

            System.exit(1);
        }

        GlobalScreen.addNativeKeyListener(new GlobalKeyListenerExample());
    }
}